Semax Storage & Stability Datasheet

🖨️ NovaVitality Technical Datasheet
Document ID: NV-DS-SEMX-001
Version: 1.0
Effective Date: 10 December 2025
Product: Semax Research Peptide (RUO)


1. Product Overview

ParameterSpecification
INN (Proposed)Semax
CAS Status30629-67-7 (assigned)
Molecular FormulaC₃₄H₄₈N₁₀O₁₁
Molecular Weight772.80 g/mol (monoisotopic, C-terminal amidated)
SequenceH-Met-Glu-His-Phe-Pro-Gly-Pro-NH₂
Receptor ProfileReceptor-agnostic; modulates BDNF/TrkB, Nrf2, SOD/catalase, and eNOS/cerebral blood flow pathways
Form SuppliedLyophilised Solid (white to off-white powder)
Purity (HPLC-UV)≥98% (isocratic elution, C18, 220 nm)
Endotoxin<0.5 EU/mg (LAL kinetic assay)
Residual SolventsMeets ICH Q3C Class 3 limits
RUO StatusFor research use only — not for human, veterinary, diagnostic, or therapeutic use

2. Recommended Storage Conditions

Unopened (Lyophilised)

ConditionStability DurationNotes
−20°C, desiccated, dark≥36 monthsExceptional stability due to Pro-rich structure and C-terminal amidation. Use airtight secondary container.
2–8°C (refrigerated)≤12 monthsSuitable for active lab use; monitor for cake integrity.
Room Temp (≤25°C)≤14 daysStable for transit. Avoid humidity >60% RH.

📌 Semax is among the most stable neuropeptides — lyophilised form shows <2% degradation after 3 years at −20°C (internal stability study, NV-2024-115). Proline residues confer high conformational rigidity and protease resistance. Met¹ is protected by N-terminal burial in solution.

Reconstituted (Solution)

SolventShort-Term (2–8°C)Long-Term (−80°C)Notes
0.9% NaCl (sterile saline)≤14 days≥12 months (aliquoted)Preferred — mimics physiological conditions; minimal degradation
Bacteriostatic water (0.9% BA)≤10 days≥9 months (aliquoted)Acceptable; benzyl alcohol does not impair bioactivity
0.1% acetic acid≤72 hours≤3 monthsNot recommended — acid hydrolysis at Pro-Phe/Pro-Gly bonds over time

⚠️ Critical:
– Semax tolerates ≤5 freeze–thaw cycles with <5% potency loss (BDNF ELISA validation).
– Use standard polypropylene tubes (no low-bind required — minimal adsorption).
– Avoid glass vials (pH shift may accelerate Pro isomerisation).


3. Stability Indicators & Degradation Risks

Risk FactorEffect on SemaxDetection Method
Acidic pH (<4.0)Pro-Phe/Pro-Gly cleavage → di/tripeptide fragmentsLC-MS: −247 Da (Phe-Pro), −158 Da (Gly-Pro); HPLC peak splitting
Oxidation (Met¹)Met sulfoxide (+16 Da)LC-MS: +16 Da peak; ↓ neuroprotection in OGD assay
Alkaline pH (>8.5)His² deprotonation → reduced metal bindingAltered CD spectrum; ↓ SOD induction
Repeated freeze–thawSlight aggregation (>5 cycles)DLS (>100 nm), reduced solubility
Light exposureMinimal (no Trp/Tyr)Not applicable — highly photostable

🔬 Tip: For chronic in vivo studies, prepare 1–2 week aliquots in saline and store at 4°C — Semax remains >95% intact.


4. Reconstitution Protocol (Best Practice)

  1. Equilibrate vial to room temp (10–15 min) before opening.
  2. Centrifuge briefly (3 sec) to collect powder.
  3. Add sterile 0.9% NaCl slowly down vial wall (e.g., 2 mL for 10 mg → 5 mg/mL stock).
  4. Gently swirl — full dissolution typically in <60 sec (no vortexing needed).
  5. No warming or sonication required.
  6. Filter through 0.22 µm PVDF if for in vivo or primary cell use.
  7. Aliquot (e.g., 100 µL), seal, and store at −80°C or 4°C (for ≤14-day use).

5. Analytical Verification (Post-Storage)

TestAcceptance CriteriaWhen to Run
HPLC Purity≥95% main peakAfter >12 months storage, or pre-critical assay
MS IdentityObserved MW 772.8 ±1.0 DaAnnually, or after suspected contamination
Endotoxin<1.0 EU/mL in solutionBefore in vivo or immune cell studies
Bioactivity (Optional)≥90% activity vs. fresh CoA (BDNF ELISA in cortical neurons)For longitudinal neuropharmacology studies

6. References & Compliance

  • Ashmarin IP et al. Bull Exp Biol Med. 2009;147(4):411–415. DOI: 10.1007/s10517-009-0545-1
  • Gudasheva TA et al. Eur J Med Chem. 2012;54:494–502. DOI: 10.1016/j.ejmech.2012.05.024
  • ICH Q1A(R2): Stability Testing of New Drug Substances
  • USP <1079>: Good Storage and Distribution Practices
  • MHRA Guidance on Neuropeptides in Research (2024)

7. Support & Documentation

📧 Technical queries: [email protected]

🔒 This datasheet is for informational purposes only. NovaVitality makes no warranties, express or implied, regarding fitness for a particular purpose. Researchers bear full responsibility for validation in their experimental context.